Fallout Report
This report allows you to examine:
Conversion rates through specific processes on your site (such as a purchase or registration process)
General, wider scope traffic flows: Of the people who saw the home page, how many went on to perform a search and then how many of them eventually went on to look at a specific item?
Correlations between events on your site: What percentage of people who looked at your privacy policy went on to purchase?
To perform the analysis, you define a series of "checkpoints" represented by specific pages on your site. The resulting Fallout Report graphically displays how many visits reached Checkpoint 1, and then how many of those eventually made it to Checkpoint 2, and how many of those made it to Checkpoint 3, etc.
PathFinder Report
The PathFinder report enables you to dissect your full site paths and look for trends, patterns, and fallout points to better understand how your users navigate your site.
Full Paths:
This allows you to find the total unique paths taken by your user while navigating the website.
For better understanding the difference and solution to your query, I suggest you to go through each of these reports individually and understand your user journey from each point and angle.
You can also refer to
The Adobe SiteCatalyst Handbook: An Insider's Guide by Adam Greco which has a full dedicated section to understand Shopping Cart journey.