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Level 3

Using LiveCycle Designer 9, go to you Window pull down menu and make sure you have your Object window open - there should be a check mark next to it, if its open.  Don't confuse Object with Object Library.

Now that you sure your Object window is open, choose your submit by email button.  You should see email address and email subject as fields.  In the email address field, delete the previous address and update to your new address.

I beleive its pretty much the same in previous versions and I don't have ES, so not sure if there would have been any change in that version.  Remember LiveCycle, not PRO for making this change.