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There are no books on LCCS yet,  but there are some online tutorials.

You can check here (http://blogs.adobe.com/collabmethods/), here (http://www.adobe.com/devnet/flashplatform/services/collaboration.html) and looks at old posts in the forum. You can also do a search on Google and you'll find other tutorials made by Adobe evangelists and some of our developers.

In any case the best way to learn is to play with the examples and ask questions to the forum.