Hi Adam,
Unfortunately, it's not quite as simple as excel to sum fields using Designer - it's all about scripts. You have to take care of a few things first: creating your numeric fields, naming those fields, and adding scripts to those fields. The Purchase Order form in Designer's samples is a good example to follow.
Here's a basic adding example if you're starting from scratch:
You have two fields you need to add: 1) Apple and 2) Orange = 3) Pear. All three items need to be "numeric fields", value/type "calculated, user can override", binding set to normal. Now, viewing your script editor for the "Pear" field, use the following script:
sum (form1.Apple, form1.Orange)
The above script again goes in your script editor, function "calculate" and language is formcalc. You'll obviously need to change the path names for your Apple and Orange fields to match exactly what you have set up. If it's not EXACT, it won't work. Again, this is just a bare-bones idea of how to sum two fields.
Good luck!